In physics, nothing can be measured exactly, so exact events are in fact impossible. Measurements are approximate, and thus have finite extent, and thus can have nonzero probability.
This whole thread is silly, The 2nd law is about probabilities which are asymptotically 0, so small in practice that we could never do experiments to frequentist probability empirically, using "jars of marbles" with more than 100 marbles", let alone trillions of trillions of particles.