To answer my own question, yes, not only would PIR on Tor Onion Service enable anonymous access of data via an anonymous connection, but there other possible uses of PIR for Tor. Notable example being "PIR Tor" — which is a Tor architecture that would change Tor from being P2P to client-server:
https://www.usenix.org/conference/usenix-security-11/pir-tor...