> Everything on my network is going to go through my firewall anyway.
Yes, and that's a very reasonable configuration.
But UDP hole punching (very widely used for VoIP, online gaming etc.) works orders of magnitude better with IPv6 than with IPv4, since there is no address and port translation to worry about.
With IPv4, it's very hit or miss, since it depends on both sides' NATs and also requires additional infrastructure (i.e. STUN discovery servers).