Is there any risks of nodes assigning same IP if there's no central DHCP?
Personally, I don’t feel the need for privacy at this level of the protocol stack, and if I did, I would not consider IPv6 Privacy Extensions to be adequate. Also, I might like to keep TCP connections alive for more than a day. Therefore, I personally prefer regular MAC-based SLAAC, or even hard-coded addresses, over randomized and rotating addresses.
And thanks to Duplicate Address Detection, before a new randomly-generated IP is used, a check is made to ensure it is not in use by someone else.
SLAAC reserves bottom 64 bits for autoconfiguration, and while incredibly wasteful it does ensure every MAC can have its own IP address
In other words, no.