From what I gather from Greek news [1], there was no separate freight track. But there is one track per direction under normal conditions. One direction was knocked off by a power failure at the time of the accident, so both directions were running on a single track for that segment. Then, some signaling-relatd failure sent two trains on a head-to-head collision.
[1] https://www.news247.gr/koinonia/sygkroysi-trenon-sta-tempi-p...