If only there were a decent way to mine the earth's core directly. There's more usable material already on Earth than the entire asteroid belt. It's just all melted together, molten and buried under thousands of miles of dirt.
1. thirty-two quintillion six hundred eighty quadrillion dollars
Of course no market would hold a price when flooded with supply, but I bet our appetite for usable energy is higher than iron. That's a harder crystal ball estimation to quantify though.
http://www.wolframalpha.com/input/?i=%28specific%20heat%20of...
Hard coded number sanity check:
http://www.wolframalpha.com/input/?i=%280.44%20J%20%2F%20%28...