Until you remember that you have datacenters that need to talk to each other and then this strategy doesn't work.
I wouldn't have any trouble ignoring middlebox software (or adding a TCP fallback with a big warning that something suspicious is interfering with the connection) but Windows and macOS still lack proper SCTP support, Linux' SCTP support has some performance issues and usermode raw sockets will probably need to bypass several OS sandboxes to be viable.
That said, in server to server connections SCTP can probably be used just fine.
IPv6 definitely got off on a rocky start but none of that has mattered for decades now. If IPv6 deployment is still such a pain, that's because of either your choices of the choices of your preferred vendors.