After branching out to my immediate interest areas (tech), a little later I ended up adding Philip Plait (bad astronomy guy), Fraser Cain and other sciencey/astronomy folks. The amazing Hangouts that these folks do a number of times/week makes me feel really lucky to have access to such a resource. Certainly having some degree of access to experts in assorted fields is nothing new thanks to the internets, but G+ has, in my view, made such interactions far more accessible.
I can only imagine that there are other groups doing awesome things with G+ who I have not yet found.