The Language Instinct is a great book, but unless the content of newer editions has changed significantly, it's more of an overview of linguistics in general, and language acquisition in particular. There's not much -- if any -- practical NLP. For example, looking at Amazon's statistically-improbable phrases (SIPs), I see nothing related to NLP, nor do I see any terms related to practical NLP during a quick glance of the book's index. The index includes references to a few pages on "statistics of language", but I honestly don't remember what those were about.
Also, the Language Instinct was written in the early 1990s, so although new editions have been released, it's a bit dated. It's a classic read for linguists and people interested in language, but I wouldn't recommend it as an introduction to NLP.