CO2 concentration seems to depend on actual location:
https://www.researchgate.net/figure/The-maps-of-global-histo...
https://www.researchgate.net/figure/The-maps-of-global-histo...
Older study https://www.sciencedirect.com/science/article/abs/pii/S13522...
... tldr a higher planetary boundary layer over cities can form under various weather conditions. That reduces mixing, and cities are large sources of CO2.
So I can say - I stand corrected, and TIL :)
Anywhere that traps smog should show similar correlations with CO2.