What are the practical modern alternatives for YAML use cased? TOML, others?
For anything that requires more complex structures, JSON5 (https://json5.org/) has been gaining traction. It's basically JSON that allows a couple of more things, including comments, trailing commas, and even unquoted keys, if you're into that.
For IaC the alternative is general purpose programming languages using declarative infrastructure APIs. E.g. TS, Go, Python with CDK, CDKTF, Pulumi. For CI are stuck with YAML for now.
Extensible Data Notation, it's to Clojure what json is to Javascript.