DHCP Option 121 Classless Static Route is not implemented (Android)
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DHCP option 121 should allow devices to be pushed additional static routes. All Windows, Linux and Apple DHCP clients on the network work as expected but not Android-based devices, and I don't see an option on non-rooted devices to add the static route (not that I really want to do it manually).
[1] - https://discourse.pi-hole.net/t/push-static-route-to-android...
[2] - https://dhcp-users.isc.narkive.com/Z6gxzMDm/static-routes-op...
Unfortunately the default gateway/router (A Nokia GPON terminator) does not support adding static LAN routes - it's more of a 'fit and forget' home-grade product and isn't too sophisticated (the available documentation's pretty rubbish too!).
The problem will go away in about a month when the Nokia is replaced with a GPON bridge and a Draytek router, then the current 67Mbit VDSL service will be decommissioned just leaving the gigabit FTTP WAN connection.