Presumably the idea is that you run into the same challenges the original author did — how to get from one scene to the next, how to direct or misdirect the reader, etc. — and by solving those challenges you understand the mechanics of storytelling at a deeper level. Since you've got the "perfect" version of the story as a key, you aren't just guessing, and there is a right and wrong answer.
He also said that, to his knowledge, nobody had ever taken him up on this advice.
But, Wolfe was a fantastic writer, and an engineer, so I assume his approach would be a practical and useful one for anyone willing to put in the work.
I just spent about 30 minutes trying to find the source of the quote, but failed. /shrug