The Oculus Quest 2 has a horizontal FOV of 97 degrees. In order for α Centauri to cover two pixels, you would need a display with 6.2179487x10^26 horizontal pixels. 621 yottapixels. Something like a hundred sextillion times "4K" resolution. And that's linear resolution, tag on some more orders of magnitude for display area.
There is a reason parallax is used to measure distance to stars, rather than directly measuring their visual diameter.