Edit: I joined Pomochat to try it out and I think chatting with strangers is probably about the worst thing to be doing on a Pomodoro Technique break. It should be done during the 25 minutes (but not every 25 minutes unless your job is to poke around in chat rooms), not on the break which ought to be used for stretching/relaxing both physically and mentally. I'm typing this during the Pomodoro but will just close the window after typing this.