The US has been physically inspecting Russia's arsenal (and vice versa) under the terms of New START:
https://www.state.gov/new-start/These inspections don't actually test the functionality, but we should have a pretty good idea of the condition of their nuclear arsenal, as they have of ours, as that is part of how MAD works.
From that page:
Implementation: The information provided through the treaty’s implementation contributes to reducing the risk of strategic surprise, mistrust, and miscalculations that can result from excessive secrecy or decisions based on worst-case assumptions. Since the New START Treaty’s entry into force, as of late January 2022, the two parties have conducted:
* 328 on-site inspections
* 24,000+ notifications exchanged
* 19 meetings of the Bilateral Consultative Commission, and
* 42 biannual data exchanges on strategic offensive arms subject to the treaty.
Treaty Duration: The treaty’s original duration was 10 years (until February 5, 2021), with the option for the Parties to agree to extend it for up to an additional five years. The United States and Russian Federation agreed on a five-year extension of New START to keep it in force through February 4, 2026. The treaty includes a withdrawal clause that is standard in arms control agreements.
Russian Compliance: Although the United States has raised implementation-related questions and concerns with the Russian Federation through diplomatic channels and in the context of the BCC, the United States has determined annually since the treaty’s entry into force, across multiple administrations, the Russian Federation’s compliance with its treaty obligations.
U.S. Compliance: The United States is in compliance with its New START obligations. The Russian Federation has criticized U.S. procedures used to convert B-52H heavy bombers and Trident-II SLBM launchers. The United States stands by its conversion procedures, which render the converted SLBM launchers and heavy bombers incapable of employing nuclear weapons thereby removing them from accountability under the treaty.