If you really want to have a less CO2-heavy stuffy indoor air, what you can use is an air-to-air heat exchanger. The idea is to get fresh air from outside, but transfer heat from the outgoing Co2-rich air to the incoming fresh air so you don't waste the heating (reverse in case of air conditioning, I suppose).
If the problem is Co2 in the outdoor air, I'm afraid that's a much bigger problem that you're not gonna solve with a tank.