For these folks changing their browser, even a little bit would be like you or I walking into the bathroom and finding the toilet paper replaced with 3 seashells. You can get past that moment of panic with some coaching but some people don't like to be helped so there may or may not be anything you can do.
My philosophy: if you're getting tasked with being the family IT department, lay down some rules: they use what you suggest or they don't get support.
With such people, you never know when they will simultaneously accuse you of "breaking" their computer and remove your access to said computer so that whatever you've done that they believe "breaks" the computer indeed becomes "permanent" and is something they can be permanently pissed at you for.
On the other hand it could be a benefit to be removed from the duty of maintaing their computer, so maybe pissing them off is a (selfish) win.