Respectfully, you've got this backwards. An equation, by definition, is an assertion that two expressions are equal. 0=1 is a logically consistent assertion, but it happens to be false. Most students will intuitively have trouble with the idea that you want them to make a false statement, even if they don't realize that, because their whole schooling has taught them the opposite.
The issue is precisely that we are teaching those students that that "an equation in essence is asking for one to find the instances when two expressions are equal". Mathematical statements don't "ask" anything, they simply are. That's a pedagogical definition, not a mathematical one, and by teaching students that, you're teaching them how to pass a math test rather than teaching them math. And there's no blame on you for that, since you're paid to teach students to pass math tests. But framing it that way doesn't teach them math, it teaches them how to guess the teacher's password[1]. It's a focus on getting an answer rather than understanding the actual axioms.
So of course students don't come up with an equation with nothing to solve, because you've taught them equations are things that only exist as things with unknowns to solve.
It might be obvious to someone who already is extremely well versed in mathematics that 0=1 is "an equation without a solution". But it's unfair to expect students who don't already have that answer to derive it, because they're working off of the wrong axioms. It's a communication failure, not a mathematical one.
[1]https://www.lesswrong.com/posts/NMoLJuDJEms7Ku9XS/guessing-t...