The composition of Mars' atmosphere is less important then getting the pressure right - at 1 atmosphere, humans don't need suits just respirators, and Earth-microbes will be more then happy to normalize things to suit them (they did it here, after all).
For Venus the big problem is water: Venus is dry. The reason it's in run-away greenhouse is because all that CO2 just will not precipitate into carbonate minerals, which to do so needs water. Again: something comets have plenty of.
The difference between the two in suitability though is the tidal lock: Mars has a day-night cycle. Venus has a day-night cycle but it's 116 Earth-days long - half the planet, if you got the atmosphere under control, would be in a freezing night for 3 and half months. You could settle it, but life would only really survive at the polls. While we can process a planetary atmosphere with plausible near-future technology and local resources, there's no known way we could "spin up" Venus (ironically a fully-tidally locked planet would have much more usable surface area as an oculus-world).