Please note that Octoprint and Klipper are at different levels of functionality. It's not a choice between the two in any way.
Octoprint is for job management/monitoring and is SUPER extensible. It gives you a web interface/camera view/manual control of the printer. You can do things like install a slicer plugin so you can drop an .stl file into the browser then it will slice and print.
Klipper is more like printer firmware. It's lower level than Octoprint.
The two can be used together.