Outside the safe operating space of a new planetary boundary for PFAS
pubs.acs.org
pubs.acs.org
Talk about cutting off one’s own nose.
Wow. That's evil.
Historically, straws were also made from waxed paper.
The issue isn't that plastic straws were banned, it is that plastic straws were banned and no additional guidance was provided e.g., mandating paper straws with natural wax coatings. This combined with corporate greed led to companies putting out the most profitable product within constraints of the law-- health and environmental safety be damned.
The first paragraph of the following article describes both types of historical drinking straws:
https://www.encyclopedia.com/manufacturing/news-wires-white-...
edit: clarity
Straws made from plant stalks simply aren’t suited to mass distribution. They aren’t uniform, can’t easily be sanitized before packaging, they’re fragile, and still leak and get soaked.
The problem isn’t “corporate greed” it’s that there aren’t good alternatives to plastic for disposable straws.
The problem isn't the cars. The problem is that we don't all live in some fantasy where people have time to sit down and eat their food and drink not on the go. If it wasn't the straws people would be complaining about the plastic coffee cup lids.
This might be a USA thing but a lot of times in restaurants they’ll bring me my drink with a straw in it and I can’t help but think “WTF do I look like a six year old?”
Something made of cellulose that breaks down more easily would be better, so long as it comes from agricultural byproducts.
*edit I’m saying this might be better because some light plastics like straws end in in storm drains and on road sides, so something that breaks down over time into organic compounds might be preferable.
And later cultures could dig it up and burn it, if they wanted to.
Stones stay around for a long time, too, but no one cares. (And fire can destroy plastic easily.)
Drinks with takeaway food here have been using that style of cup for years now.
- Straws use disposable plastic
- Replacement paper straws are coated with a toxic chemical
- Straws are only necessary so that we can drink sugary drinks
- Sugary drinks don't even taste that good, and also cause diabetes and tooth decay
The problem with plastic straws, if you believe their opponents (whose claims I have not evaluated), is that they are persistent pollutants that harm animals. If paraffin-waxed paper straws are not, that's an improvement, petroleum or no.
Or just make it part of a general carbon tax.
I didn’t expect capitalism to be Fermi’s Filter, but kind of makes sense.
Clearly we shouldn’t use PFAS in straws, but waxed straws are awful.
Yes, crude oil isn't the only source of wax, and neither it is the only source of plastic.
However, if you make wax out of something, you can't make anything else out of the same material.
Plastic straws are really light-weight. Waxed paper uses a lot more material.
What’s the point of an EPA guideline if we’re literally flossing with it?
This seems to be the study that first found an association between Oral-B flossing and higher levels of PFAS in the body;
https://drtungs.com/products/113-activated-charcoal-floss.ht...
Not that that same risk applies to dental floss (I don't think many people heat their dental floss to a few hundred degrees), but your statement was more general than that.
So "the most nontoxic" is pretty darn accurate. PTFE is substantially less toxic than air, water, table salt, cellulose, polypropylene, or pretty much anything else you're likely to put in your mouth.
If you tried that with oil you would have an enormous cloud of smoke - and the smoke from the oil is MORE toxic than the smoke from the PTFE.
So yah, the most nontoxic is completely correct.
And BTW, it is far safer for your birds to use PTFE cookware vs oil because you would have to get the PTFE much hotter vs the oil for there to be any issue.
I don't think it's necessarily true that cooking with PTFE is safer, even if the smoke is more toxic to birds, because the PTFE fumes are invisible, so you can kill your birds before you realize that there's a problem. It's not likely but it's possible.
I also don't think it's really true that you have to heat PTFE "to almost glowing". WP says PTFE starts to decompose around 350 degrees (science) and is already a health problem for birds above 250 degrees, killing parakeets at 280 degrees (after four hours of exposure, which was longer than it took burning butter fumes to kill the parakeets). See https://en.wikipedia.org/wiki/Polytetrafluoroethylene#Safety. Things don't start to glow until about 525 degrees, or a little hotter if they're very white.
The difference between 280 degrees and 525 degrees is even bigger than it sounds in terms of heat input. It's 145 degrees, yes, but at those temperatures radiation (in the infrared) is the dominant form of heat transfer, and radiation is proportional to the fourth power of temperature; at 280 degrees blackbody radiation is 5300 watts per square meter, while to get something up to 525 degrees you have to pump in 23000 watts per square meter, more than a factor of four.
The summary is that it takes four times as much heat per minute to make your teflon skillet glow as it takes to heat it up enough to kill your parakeet in four hours, which is about the same temperature that soybean oil starts smoking at, so if you have birds you might want to think about switching to cast iron, or at least always using abundant oil on your teflon so you're guaranteed to notice if you go outside the safe temperature region.
None of this is relevant to bike chain lube or dental floss.
PTFE is completely safe.
Microplastics of PTFE, particularly fibers, provoke the same sort of response as similar asbestos, for the same reasons. A smooth PTFE surface, e.g. in a surgical implant, evokes a completely different response.
So, no: PTFE can be safe, but is not necessarily. Convexity matters.
PTFE is soft and not sharp, completely the opposite of asbestos which is both needle sharp and very hard and stiff.
Not to mention no one is making microfibers of PTFE, the fibers are much larger that that.
The principle, as I recall, is that when a nanoparticle or nanofiber lodges somewhere, poking a membrane or anyway intruding, immune system cells attack it with increasingly caustic chemicals, trying to break it down. If it is too stable, they fail, but don't give up. It is this inflammatory response that underlies asbestos's toxicity.
A smooth, locally flat surface does not, by itself, provoke that immune response, and chemically PTFE doesn't draw attention. But PTFE happily adopts any shape. So, maybe nobody makes PTFE microfibers or nanoparticles on purpose, but that doesn't mean there aren't any.
The short story is that tests showing PTFE surgical implants don't evoke an inflammatory response do not tell you much about effects of PTFE in different circumstances. Likewise: people can wear metal jewelry for years, but that doesn't mean you can poke a knife through somebody with no effect.
There was a recent report that those mesh tetrahedral tea bags each release literally billions of plastic nanoparticles into your tea. That cannot have been deliberate. I wonder if those have been banned or recalled yet...
I think yesterday the news were about if it was safe to breastfeed while you may have heightened levels of it. The new guidelines was retracted because most of the scientists behind it disagreed with the conclusion based upon newer evidence. So it getting a reevaluation
The top PhDs from the biggest chemical companies can not even keep pace with the analytical needs of their own production units.
And relatively speaking they have a virtually unlimited budget.
There's technical debt in natural science still hanging for decades awaiting progress.
- Ample evidence of health hazard (with seeping of PFAS into ground water) - Temporary shutdowns - Environmental fines
both 3M factories are still very much in operation:
Zwijndrecht, Belgium Dordrecht, Netherlands
Other safety standards have also been lower in the USA but I'm not sure if that still holds up today.
There's also the space problem: many American cars have trouble fitting onto European roads and parking spaces because the USA has dedicated a lot more space for cars as a result of city design often practically forcing you to own a car. The EU has its SUVs but most of them are small in comparison to the unimportable American ones,
What happened with 'dieselgate' was that many manufacturers got caught in what amounts to very blatant fraud, faking that they were compliant with the environmental standards for tailpipe emissions when they were in fact completely off the charts.
Red is the legal limit!
Manufacturers had firmware that detected if the vehicle was in a test chamber (front axis moving but no G forces), if that was true then engine management would enable full emissions control and limit engine performance. If that was false the emissions control would be dropped and you would have all the horse power and acceleration that customers so dearly love.
I will say it explicitly: Whenever you see in the media the discussion on 'defeat devices', what it means is that manufacturers performed large scale fraud, _by_design_. I think people really fail to appreciate how severe this was.
The 'discrepancy' they discuss in the press release you link is just a euphemism to say, we don't want to go bankrupt and disrupt German GDP but we can't sell a car that complies with emissions regulation (i.e. not killing people ahead of time with air pollution) without making it have the engine performance/acceleration of a dead mouse.
I'm referring to the following sentence in the abstract:
> Levels of PFAAs in atmospheric deposition are especially poorly reversible because of the high persistence of PFAAs and their ability to continuously cycle in the hydrosphere, including on sea spray aerosols emitted from the oceans.
https://pubs.acs.org/doi/10.1021/acs.est.1c04277
I'm still digesting this one and would appreciate input from anyone else who wants to read it.
As someone who lives close to the ocean, I'm concerned about the long-term health effects. I guess I'm probably breathing sea spray aerosols all the time. I can hear and see the breaking waves from my home.
Big tech has a big PFA problem
Ski Wax PFA is much worse. https://www.sciencedirect.com/science/article/pii/S004565352... those are just left to be shed in the snow, and they don't vanish once they are in the snow.
https://ceramics.org/ceramic-tech-today/ceramic-video/video-...
Not to stray from the main discussion but biocompatible has a pretty narrow scope.
Time effects are not always fully captured, it often boils down to quite literally "we injected this stuff in 50x bunnies' bloodstream or implanted under their derme and none of them died after a month".
With any new substance a cautionary principle should be applied, the main issue is Industry is spitting out new substances faster than we can meaningfully study them.
https://www.fda.gov/medical-devices/biocompatibility-assessm...
https://www.fda.gov/medical-devices/science-and-research-med...
That profile now looks very complete but before we had all those RCTs and clinical surveilance data, someone had to make a decision on wheather or not we can use PTFE in vascular stents _for_humans_. That decision would have relied on initial animal tests (i.e.literally sticking this stuff in bunnies) and some limited trial data.
My point is not that FDA are somehow clueless bureaucrats but that everytime we introduce a new substances we are taking an educated risk based on limited (animal) data.
Apparently they have some improvement in the pipeline that will bring about really PFAS-free product in the next few years or so. https://saferchemicals.org/2021/09/30/gore-tex-manufacturer-...
Cheeky buggers indeed haha
https://en.wikipedia.org/wiki/Planetary_boundaries
The first sentence suggests that the study's authors are concerned that PFAS and its similar cousins represent a non-linear, large-scale environmental threat.
Since that's a catch all category for many things (nuclear waste, other synthetic chemicals, there's even debate with the original authors of the framework if Artificial Intelligence should be considered), the boundary value itself is not currently defined.
One school of thought is that the boundary value for this category should be zero - as any synthetic substance is more than nature generates.
Regardless, papers like this one are helpful to piece together all of the novel entities research amd get a better picture of how this boundary interacts with the rest of the Earth System.
It's also interesting how it's the political "conservatives" who seems to be most accepting of these kinds of environmental changes, when "conservatism" is supposed to be about preserving the way things are now, or perhaps how they were in some recent "golden age" past, as I understand the term.
"Planetary boundaries is a concept highlighting human-caused perturbations of Earth systems making them relevant in a way not accommodated by the environmental boundaries separating the three ages within the Holocene epoch."