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If it repels water that well, how is going to be for breathability and moisture coming off the body wearing the treated clothing?

Moisture off the body would just run down the inside of the garment presumably. As for breathability, that may be an issue.

That sounds pretty much the same as a plastic garbage bag. Sounds delightful.

The sweat collects in your shoe and at the end of the day you wash your shoes.

Why wash? If the shoe is coated in NeverWet you just pour out the moisture, right?