Photovoltaic Solar Panels (1905)
lowtechmagazine.com
lowtechmagazine.com
https://www.energy.gov/eere/solar/linear-concentrator-system...
The Crescent Dunes CSP plant in Nevada had a number of stumbles, but appears to be generating power again:
https://en.wikipedia.org/wiki/Crescent_Dunes_Solar_Energy_Pr...
Their solution of storing thermal energy in molten salt isn't exactly low-tech, but other CSP systems use cheaper thermal storage materials like sand or basalt, which avoid the geopolitical and environmental problems of lithium extraction. Of course, PV panels can dump power into thermal batteries too. Maybe PV farms with huge thermal batteries of sand or basalt will be the best long-term grid-scale solution.
For storage, there are many other ways to store energy and that too is driven by cost. Dumping heat into salts, basalt, etc. are all attractive propositions from a material cost point of view. Converting heat back into energy is somewhat inefficient however. But these systems are great for providing long term energy storage for e.g. heating systems needed in the winter.
Of course, winters in Nevada are pretty short and warm. I visited Las Vegas in the middle of the winter once. It was very warm. Reno is a bit colder but also has short winters.
Yep, that's how I first heard of it. Finnish company providing sand-based thermal energy storage:
https://newatlas.com/energy/sand-battery-polar-night/
For electric generation, there's this Danish company whose system integrates turbines run off reheated air:
https://www.stiesdal.com/storage/the-gridscale-technology-ex...
They claim to be deploying a 4MW demonstrator unit sometime this year. As I imagine it, a system like this one could charge smaller (in-home) batteries that provide immediate power on demand. As the batteries begin to drain, the turbine has time to spin up. The chemical batteries act as a buffer for turbine downtime and/or response time. Sort of like a Prius hybrid powertrain. The required chemical battery capacity would be much smaller than, say, a grid-scale lithium ion battery bank.
We don't need low-tech options. We have all that tech that we can use right now. Instead, the non-viability of all low-tech options is exactly what led us into this grave global warming situation we are.
Low tech has a simple supply chain, high tech has a complicated one.
However, when I last did the calculations, passive CSP is much better at hot water generation for industrial applications - leather/textile factories need a lot of hot water or steam. CSP can at least cheaply pre-heat if not fully heat or boil the water.
Once you start storing lower temp heat, not intended to generate electricity, then its totally abstracted from the input, you just use grid electricity which can be solar, wind, nuclear or industrial waste heat and locate them anywhere, not just desert locations.
But more importantly, there are no real geopolitical or environmental problems with lithium. It's abundant and recyclable. We're using it because the alternatives are so bad for the environment. Literally killing people, plus animals and ecosystems.
Evo Morales might disagree on the first point:
https://www.nytimes.com/2021/12/16/business/energy-environme...
Just like we talk about "Banana Republics" rather than "Worker Mistreatment Republics".
Maybe it's the people who don't want to pay the market price for things and respect environmental and worker regulations when they can topple democratic governments for less cash that are the real "geopolitical problem" not the lithium and bananas?
I mean what could we possibly do if a country with Lithium jacked the price up? Buy it from all the other countries with the broadly distributed Lithium deposits? Mine it in our own countries which also have Lithium? Then we're back in the problem situation of having to treat the workers like human beings and pay standard market rates.
I don't think it would take many drones to eliminate this, though. Birds don't like coming near drones and when you have a huge tower with oversight of the region you need to protect, finding the birds well before they combust seems tractable.
https://en.wikipedia.org/wiki/Concentrated_solar_power#Effec...
https://cleanenergywiki.org/index.php?title=Cuprous_Oxide_So...
https://babel.hathitrust.org/cgi/pt?id=mdp.39015051407073&vi...
It's entirely possible for a tech to be more sustainable than another tech, yet not be perfectly sustainable.
Gas can be better than coal, wind can be better than gas and so on without having to continually harp on the exceptions and edge cases to the point that the truth gets lost.
Solar panels are recyclable and have become much more sustainable over the decades. To say otherwise is absurdly wrong.
edit: they link to one of their own articles about PV sustainability, which contradicts what they said in the preceding paragraph, so it might just be really bad writing:
> Meanwhile, solar cells are becoming more energy efficient, and the same goes for the technology used to manufacture them. For example, the polysilicon content in solar cells -- the most energy-intensive component -- has come down to 5.5-6.0 grams per watt peak (g/wp), a number that will further decrease to 4.5-5.0 g/wp in 2017. [2] Both trends have a positive effect on the sustainability of solar PV systems. According to the latest life cycle analyses, which measure the environmental impact of solar panels from production to decommission, greenhouse gas emissions have come down to around 30 grams of CO2-equivalents per kilwatt-hour of electricity generated (gCO2e/kWh), compared to 40-50 grams of CO2-equivalents ten years ago. [7-11] [12]
The question revolves more around whether they are actually recycled.
From the article: >Silicon cells can only be recycled by a combination of thermal, chemical, and metallurgical steps. That is an expensive process with an impact on the environment. Although you can find statements claiming that around 10% of solar panels are “recycled", they are more likely to be “downcycled”. The modules are shredded, and the resulting material is used as a filler material in asphalt and cement industries.
Oh no, does that involve thermal steps? It probably involves those suspicious sounding "metallurgical" steps too, what even is that, it sounds positively diabolical.
Wait, chemicals? No one told me they had chemicals in them. I never touch anything with chemicals in it. Totally banned them from my life. They are well known to cause cancer apparently.
Can be, not necessarily are.
Check "Recycling Process" here:
https://www.epa.gov/hw/solar-panel-recycling
Particularly:
>The industry is new and still growing, with researchers examining how to commercialize recycling to economically recover most of the components of a solar panel. Elements of this recycling process can be found in the United States, but it is not yet happening on a large scale.
The question revolves around the existence of suitable recycling plants and whether the capacity of these plants is enough (particuarly in times when a "first generation" of panels is progressively approaching an "end of service life").
See also:
> Many of these components can be recycled. Glass composes most of the weight of a solar panel (about 75 percent), and glass recycling is already a well-established industry. Other materials that are easily recyclable include the aluminum frame, copper wire, and plastic junction box.
Which is almost exactly what I said, with a few extra details and less sarcasm about "chemicals'.
The BIG doubt is IF they are actually recycled (as in the main article probably largely "downcycled").
As per the EPA site (and also the other thread I linked to), they are NOT recycled (at the moment), or - even if they are - they are not - yet - recycled on a large scale.
Here it is an article by MIT (2021) stating how only about 10% of discarded panels are recycled:
https://www.technologyreview.com/2021/08/19/1032215/solar-pa...
and, soon, the amount of discarded panels is going to increase.
> Perovskite solar cells hold an advantage over traditional silicon solar cells in the simplicity of their processing and their tolerance to internal defects. Traditional silicon cells require expensive, multi-step processes, conducted at high temperatures (>1000 °C) under high vacuum in special cleanroom facilities. Meanwhile, the hybrid organic-inorganic perovskite material can be manufactured with simpler wet chemistry techniques in a traditional lab environment.
https://en.wikipedia.org/wiki/Perovskite_solar_cell#Processi...
PS. OTOH I wasn't aware that Si based panels might have lead in them, too (even though much less?) as per https://news.ycombinator.com/item?id=32283432
According to the article, the best iteration of Cove's invention achieved 5% solar-to-electricity conversion using an antimony alloy. Modern silicon solar panels achieve over 20% solar-to-electricity conversion using silicon. Silicon is non-toxic and is more than a million times as abundant in the Earth's crust as antimony [1]. Silicon solar cells do not contain toxic compounds. Modules made with silicon cells may contain toxic compounds if they were older ones manufactured (pre-RoHS) with lead based solder or glass frit containing lead, but the same issue would apply to antimony based solar modules; the cell material is not related to the soldering technology. Every other criticism of silicon given in the article (mining, complex machines, global supply chains, fossil fuels used upstream) would equally apply to a hypothetical antimony-based solar industry of comparable scale.
Low Tech Magazine is a great source for introducing modern audiences to old forgotten technologies. But it has apparently run short of forgotten technologies that may actually be better and has fallen into a rut of exaggerating contemporary-technology drawbacks and minimizing the problems of old technologies.
[1] https://en.wikipedia.org/wiki/Abundance_of_elements_in_Earth...
This is absolutely untrue. The silicon is just the starting base, you still need to dope the cells, often with an arsenic compound (Indium-Gallium Arsenide, Gallium Arsenide, etc.)
In the EU and California, solar panels are exempt from RoHS requirements.
I used to manufacture solar panels for Sunspark Technology in California. You can't get the same kind of conductivity using tin bus ribbon without sacrificing usable cell area, as you need a wider, flat strip of tin, compared to lead. The newest "invisible bus bar" panels are using silver wire. These cells, when I worked there pre-COVID, were dumping ~11A at full light exposure. The inter-string bus bars were lead-coated copper, as were the string to junction box interconnect ribbons. 60/40 was used in the junction box. We manufactured panels for everyone, including Jinko, that behemoth of a solar corporation.
Solar panels very often have toxic stuff everywhere.
On further reading I find that you are correct about RoHS exemptions for lead in solar modules:
https://www.pv-magazine.com/2019/12/07/the-weekend-read-taki...
I appreciate the correction.
> In the 1970s and 1980s, scientists investigated Zn4Sb3 for use in photovoltaics and concluded that the material’s “obvious advantages are apparent simplicity and relatively low temperature of the preparation procedure.” [23] The melting point for Zn4Sb3 is 570 degrees Celsius, while it’s 1,400 degrees for silicon.
> Silicon modules are sandwiched between two laminate encapsulant layers (usually EVA, an ethylene/vinyl acetate copolymer). These layers are essential to ensure module service lifetime. [1-3] To recycle the silicon – the most valuable component of a solar panel – these layers need to be separated, but burning them also destroys the modules. Silicon cells can only be recycled by a combination of thermal, chemical, and metallurgical steps. That is an expensive process with an impact on the environment. [...] In contrast, the solar cells built by George Cove were entirely recyclable. They required no protective layer and did not even contain solder.
> Schottky cells do not require a high-temperature phosphorus-diffusion step, which ordinarily creates the n-layer of the p-n junction in silicon today. This alone reduces the energy input into the solar cell production process by 35%.
... and a point that maybe that efficiency of Schottky cells (irrespective of composition) hasn't really been explored:
> Scientists also reached 17% experimental efficiency for a graphene/silicon Schottky cell, up from 1.5% ten years earlier.
"Silicon Schottky photovoltaic diodes for solar energy conversion"
https://ntrs.nasa.gov/api/citations/19760005411/downloads/19...
Here's a very early (1953) review of photovoltaic cells that includes Schottky barrier cells:
"Photovoltaic Cells and Their Possible Use as Power Converters for Solar Energy"
https://citeseerx.ist.psu.edu/viewdoc/download?doi=10.1.1.52...
There are a couple of problems with the implications given by the quote
Schottky cells do not require a high-temperature phosphorus-diffusion step, which ordinarily creates the n-layer of the p-n junction in silicon today. This alone reduces the energy input into the solar cell production process by 35%.
Reducing the solar cell energy inputs by 35% is a clear win only if the cell output does not fall commensurately. A record 17% efficiency for a Schottky cell compares to over 24% record efficiency for PERC cells made with conventional high temperature phosphorus diffusion:
"Trina Solar claims record 24.5% efficiency for 210mm PERC cells"
https://www.pv-tech.org/trina-solar-claims-record-24-5-effic...
That means that the best Schottky cell generates about 69% as much energy as the best PERC cell while taking about 65% as much energy to manufacture. The Schottky cell generates about 7% more output energy per unit of input energy -- a pretty marginal improvement.
There is a more promising alternative to high temperature diffusion cells already in mass production: the heterojunction solar cell. It was originally commercialized by Sanyo (later acquired by Panasonic) but its patents have recently expired so several manufacturers now make heterojunction devices.
Major solar manufacturer Longi just set a cell efficiency record of 26.5% with a heterojunction design:
https://pv-magazine-usa.com/2022/06/24/longis-heterojunction...
Heterojunction cells are processed at low temperature because the delicate amorphous silicon layers cannot withstand high heat:
"Silicon heterojunction (SHJ) solar cells have typically a low process temperature limit (~250°C) because high-temperature annealing processes can degrade the passivation of the hydrogenated amorphous silicon (a-Si:H) due to the hydrogen effusion during the annealing."
(From https://www.intechopen.com/chapters/61900)
Given the combination of low temperature processing and high efficiency found in heterojunction cells, I am personally doubtful that the Schottky barrier cell can offer superior energy return on energy invested for solar power systems.
However, a major area of advancement on the horizon is multi-junction panels. These stack different semiconductors which each harness different wavelengths of light to harness more of the sun's relatively wide band of light.
I'm not sure exactly what junction chemistries we'll see in these going forward, but I'm sure the industry will be trying out just about every configuration we can manufacture.
No man: https://www.smithsonianmag.com/sponsored/brief-history-solar...
Man: https://babel.hathitrust.org/cgi/pt?id=mdp.39015051407073&vi...
If you photoshopped the man out, you wouldn't also add the wire and tape.
Look at the reflection of the man in the solar panels. The reflection is great - far better than what I would expect from 1905 technology. Also, the caption of that photo says it "contains Mr. Cove", so the photographer included a picture of a human in the picture.
I suppose the original may have included a human, but not that human.
Amazing.
"Like the coal and oil, water power is not within the reach of the average man. If he is to use it in the future he must buy it from the capitalist as he does now from the coal baron or the oil king. It is difficult, however, to see how any commercial corporation or combination can monopolize the direct rays of the sun." (Quote attributed to Winthrop Packard, 1909. See Ref#19 in [0])
[0] Title:George Cove's Solar Energy Device. Author:Dennis Bartels. Footnotes: [https://journals.lib.unb.ca/index.php/MCR/article/view/17744...]
This is pretty much a solved problem.