On weekdays here in California, A/C usage and grid stress both peak around sunset, just as PV output flat-lines.
Surely it will use all of the magic grid storage in place that renewable promoters always talk about.
Adding more entropy to the system isn’t really the answer. Cooling people before rooms is a better answer.
Unless there are dogs involved, in which case you'd cool them before people, or just cool the room and everyone is comfy.
Machines to gather resources to build factories of machines for workers to drive to, their cars needing a similar concept to exist, to build ACs is a huge part of their problem.
Physical laws of the universe are well defined at this point.