Some older books might be useful, though I'm not sure how useful older python books might be.
Since you're a librarian, may I suggest some books you might want to consider keeping (not all of these are programming books per se):
Designing Data Intensive Applications, by Martin Kleppmann
K&R for C
K&R The Practice of Programming
The Art of Unix Programming, by Eric S. Raymond
The Cathedral and the Bazaar, by Eric S. Raymond
Code: The Hidden Language of Computer Hardware and Software, by Charles Petzold
The Soul of a New Machine, by Tracy Kidder
The Idea Factory, by Pepper White
The Little Schemer, by Friedman and Felleisen
SICP, by Sussman and Abelson
Introduction to Algorithms, CLRS
The Algorithm Design Manual, by Steven
Introduction to the Theory of Computation, by Michael Sipser
The "dinosaur book", "dragon book" etc.