1. Ice thermal storage. You freeze ice at night and melt it during the day to cool your building. Only used for large buildings - check out Chicago's district cooling for an awesome example.
2. Adiabatic and hybrid cooling towers. These are HVAC equipment that can switch between regular and a "wet mode" where they evaporate water to cool the AC coil and reduce electricity usage.
3. Better automation tools. Building automation systems are fully programmable (e.g., switch schedules when outdoor temperature is past a certain threshold), unlike most programmable thermostats which can run a fixed schedule but not much else.