I like your point about the emergent complexity from many-layered systems.
The human equivalent would be if you could create two molecularly identical brains, and have them experience the exact same lives for some time, controlling all stochastic processes, would they be the same person? Obviously it's not possible to control these things in the physical world, but even if you did get the same person, that doesn't make either any less sentient.
People always ask if the brain is a computer, decide it is not, and come to the conclusion that sentience would not work on a computer. I think the universe is the computer / algorithm and the brain is the data being fed into it, which leads me to say consciousness can exist digitally.
Why is determinism even relevant?