If you are taking air, running it once through a filter, and using the air that comes out for an application that needs very few particles, then a 99.99% filter is “10x” as efficient as a 99.9% filter in the sense that the air coming out will have 1/10 as many particles. For example, a 99% efficient face mask is “10x” as efficient as a 90% efficient mask (assuming both fit perfectly, which they don’t, although a PAPR approximates a perfect fit).
But an air purifier doesn’t do this at all. It continuously sucks in air, removes particles from it, and sends the filtered air right back into the room to mix with all the other air. The performance of a 95% filter in this context is barely distinguishable from that of a hypothetical 100% filter. Your characterization would have the 100% air purifier being “infinitely” more efficient.