The Startship's booster has a propellant mix of 2800 tons of oxygen and 800 tons of methane [1]. Since in the reaction CH4 + 2 O2 = CO2 + 2 H2O there's 4 times as much oxygen by mass (2x32 = 64) than methane (12+4=16), it follows that only 700 tons of methane burn, and 100 are vented in the atmosphere.
This might not seem like much, but Musk has a goal of 1 million launches per year [2]. The EPA considers that one ton of methane is equivalent to 25 tons of CO2, so that brings us to 2.5 Gigatons of equivalent CO2 emissions.
Currently the whole of the US emits 6.0 Gigatons equivalent CO2.
Take a moment to ponder this.
[1] https://en.wikipedia.org/wiki/SpaceX_Starship#Super_Heavy_bo...
[2] https://techcrunch.com/2020/01/17/elon-musk-shares-details-a...