LiFePO4 is great - especially as an addition to solar systems currently using lead acid.
If you add a couple of LiFePO4 batteries before your lead acid (you should do some basic math where you have enough LiFePO4 to last about 1-2 days, depending on your location, without having to hit the lead) using a DC-DC charger (which does reduce efficiency - but that's ok) you increase the size of your pack, really help pull ALL the power out of your solar that you can, add a very safe battery (LiFePO4 is really safe compared to traditional lithium), and best of all, you really, really, really extend the lifespan of your lead.
I mean like, you probably will never be able to kill your lead doing this, for multiple reasons: primarily, you're just not using it that much, but you're also really keeping it topped off when you do use it.
The key is that lead acid isn't great at sucking up charge when it is 80-100% charged. So it is really hard to "catch up" charge with solar, even if you have a ton of it. Solar is not going to put out more than it draws. So if your batteries will only accept some X of AMPs to charge, that is all you're getting (well, you can use extra power for other stuff when this is happening, if you're set up that way, like powering appliances, so you can get some benefit still).
However, with LiFePO4 - that bad boy will take all the power you can throw at it (well, not technically, but for the purposes of a solar array, sure) and top off really quick. Then, when the sun is down, it charges your lead.
I think the benefits of this is more important for smaller arrays with fewer lead acid batteries, and where the LiFePO4 battery will be a single $500 100ah battery (rather than 10 of those), but I imagine even in large large setups this could really help.
LiFePO4 is amazing but I think the cheapest you can go right now by buying used server rack equipment is like $250 for $100ah? So 2.5x or more the price of lead, and you're comparing a used battery vs a new battery (and with the lead, $100 will probably get you a reputable battery, not some no-name used LiFePO4 battery).