OTOH, your personal application configuration files (editor, window manager, etc.) can nearly always be copied as-is without causing any problems. Some people have been copying the same .emacs from machine to machine for years, if not decades, upgrading Emacs all the while.
To learn how Linux works, I would recommend Linux internals, because from skimming the TOC, it seems similar to "UNIX internals, the new frontiers". The latter book does not mention Linux, but probably learns you more about what I would describe as "how Linux works" than this book.
This book is more of a 'how do you build a new distribution from scratch'. Doing that will learn you a bit about the userland tools and their dependencies. That can be fun to do and useful, but it is a different thing.