Graphene may have found its killer app
economist.com
economist.com
[1] https://particleandfibretoxicology.biomedcentral.com/article...
More info: https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4740125/
In about a decade or two brake dust pollution will be more recognized as a severe public health problem. It's not on the hype cycle yet. https://pubmed.ncbi.nlm.nih.gov/32593898/
From Fig 2. of https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7789336/
Mechanism of DNA methylation and histone modification alterations induced by nanomaterials and nanoparticles:
Exposure to NMs and NPs alters the functioning of chromatin-modifying proteins, e.g., DNA methylation and demethylation machinery, and histone-modifying enzymes, causing changes in the pattern of DNA methylation and histone modifications.
One of the most common effects of NMs and NPs is the induction of cellular stress, e.g., oxidative and endoplasmic reticulum stress, and metabolic disturbances, e.g., one-carbon metabolism and the citric acid cycle.
These events are causing DNA damage and repair response and metabolic alterations affecting the functioning of chromatin-modifying enzymes.
Any or all of these events may result in hypomethylation of DNA and altered histone modification patterns.
Additionally, exposure to NMs and NPs causes activation of the inflammatory response that, in turn, may cause DNA hypermethylation and histone modification changes
I wonder whether graphene, itself a flat carbon compound, has the same affinity for DNA?
Pure carbon really isn't something that a lot of organisms ever encounter.
Also caused by an additive (alumina) that made concrete stronger, but turned out later that it started to rot like crazy when it gets wet
The way to make this better is to be able to have mixes with lower fractions of cement for a similar level of strength - hence using graphene in this case.
Was trying to make a 30cm x 60cm hole in a DIY concrete wall that the last owner of my house had placed over the mains pipe that was leaking from two joints underneath it (I suspect he also DIYed the piping, given its rather unorthodox setup). I had to make room for a plumber to access it.
It was poured in the early 70s, looked pretty, well, homemade, so I figured, easy! Borrowed a concrete breaker, got to it.
3 weeks, very painful wrists from the vibration, and a hired concrete saw, later, I finished my hole.
But holy crap, I had vastly underestimated concrete.
I'm still a bit at loss why Climeworks or Prometheus Fuels would pump ginormous amounts of normal air through their respective setups to extract the 0,0004% of CO2 instead of feeding from pure CO2 by industrial processes like this one.
It seems like an easy win on the low hanging fruit to me, and I think there's work on making that practical from Noya Labs: https://techcrunch.com/2021/02/24/noya-labs-turns-cooling-to...
Since pumping CO2 into the ground is technically just that (even if they don't really care much whether it actually stays there and oil comes out in the process).
Generally the solution to these problems whether it's co2 capture or power to gas at scale is not some future way to defy physics or edge our way up in efficiency towards a distant future where it might be viable but to just emit less. I suspect we'll look at this in the future the same way many look at the plastics industry's takes and propaganda about recycling.
I think the way we designed cities around cars could really stand a serious second look. Cars are really a necessary evil for me. I just bought one after 6 years of not having a car. I wish I didn't need it.
More seriously, sorry to hear about the car. It sucks to be that way. I've always been lucky enough to arrange my life around access to public transport (I don't drive) but I've been tempted many, many times.
Good propertyy. It would be even better if the material acted as a good insulator. And be re- or upcyclabe when we need to tear down the building. And while we're at it: it would be nice if the product would just grow...
That sounds like a tree to me...
https://www.nytimes.com/1981/09/23/business/the-rise-of-mini...
We should use more wood.
https://en.wikipedia.org/wiki/Glued_laminated_timber
Consider this picture:
https://en.wikipedia.org/wiki/Glued_laminated_timber#/media/...
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The "Glulam versus steel" section is really interesting!
> A 2002 case study comparing energy use, greenhouse gas emissions, and costs for roof beams found it takes two to three times more energy and six to twelve times more fossil fuels to manufacture steel beams than it does to manufacture glulam beams. It compared two options for a roof structure of a new airport in Oslo, Norway: steel beams, and glulam spruce wood beams. The life cycle greenhouse gas emission is lower for the glulam beams. If they are burned at the end of their service life, more energy can be recovered than was used to manufacture them. If they are landfilled, the glulam beams are a worse alternative than steel because of the methane emission.[9] A more recent study by Chalmers University of Technology was not so optimistic. Nevertheless, it showed that while the absolute greenhouse emissions are strongly dependent on the method used to calculate them, the environmental profile of glulam is typically as good as or better than steel in an example structural application.[10] The cost of the glulam beams is slightly lower than the steel beams.
It seems like people are using them, so I presume it's safe. I don't think I would want to live in them until we've seen a bunch of them catch on fire. I'd probably be fine with it up to 3 stores, but anything higher would make me concerned.
Increased efficiency will lead to more use, not less.
Graphene flakes are all that is needed for concrete reinforcement, and it's trivial to produce, even at scale. Carbon chunks are thrown into industrial blenders with water and detergent, resulting in graphene flakes sheared and then separated in suspension. The flakes are separated, washed, and dried.
Large graphene sheets are hard. Tiny flakes are trivial, gradeschool kitchen science.
Concrete is very weak in tension. That's why it's basically never used without steel reinforcement. I think increasing the tensile strength is mainly useful to prevent cracking which looks bad and can allow water to get to the steel.
"And when, eventually, these things do reach the ends of their lives, if the graphene can be recovered and used again it would be a welcome boost to building a circular economy."
This just sounds silly/unfeasible.
[1] https://www.frontiersin.org/articles/10.3389/fmats.2022.8616... [2] https://www.nature.com/articles/s41598-019-42761-2
So each gram of graphene reduces about 300 grams of concrete.
Concrete looks like it costs about 5-10c per kilo.
Graphene costs around $200 per kilo.
So yeah, we're about an order of magnitude off, even if some of my numbers above aren't precise. It will either require a large price fall in graphene, or serious carbon taxes on concrete.
Reduces the need for structural concrete by about 30%. Graphene makes the concrete stronger. That is important but not the entire purpose of concrete. Lots is used as space filler, liquid rock to seal against wind/rain/snow. Concrete is also used because it is heavy. Making it stronger won't reduce its use as a heavy anchor point for a structure. A giant wind turbine needs more than a strong base, but a literally massive one to prevent tipping over in strong winds. Graphene infused or not, that base still needs to weight the same.
[1]https://www.chemistryworld.com/news/graphene-slips-deeper-in...
The article actually mentions a company called Levidian. Apparently, they produce thousands of tonnes of graphene per year already. I'm sure they are not the only one. Somebody is buying that stuff and using it for something. A core usecase for this company seems to be carbon capture. The founders of this company were involved with the ground breaking research that lead to discovering how to produce graphene.
Also, that's less than 20 years ago. They were messing around with sticky tape and graphite in 2004. The people that did that got their Nobel price in 2010. From there to thousands of tonnes produced per year in the space of 18 years is actually kind of impressive.
> Also, that's less than 20 years ago. They were messing around with sticky tape and graphite in 2004. The people that did that got their Nobel price in 2010. From there to thousands of tonnes produced per year in the space of 18 years is actually kind of impressive.
If anything, it's a pre-millennial attitude - the 20th century was the era when people got used to astonishing advances every few years, and the space race was preeminent in this.
1957: Sputnik 1 1969: Moon landing 1981: Space shuttle 1986: Mir space station
To a layman who has seen the above, 20 years to develop a space elevator sounds perfectly reasonable and even conservative.
(do)
Personally I enjoyed the politics and the society building and didn't care much for endless descriptions of rocky landscape.
to me, the hilariously boring part was the convention where they deliberated over the constitution. too accurate. also the constant repetition of people getting lost in the wilderness and having a vision of Hiroko...
it took me almost a year and a half of quitting blue mars before i finally finished. he just really needed a more judicious editor.
hah, just noticed your username. i put off dune forever until finally watching the movie... half way through god emperor now. i think the politics and philosophy of dune are even more interesting than mars, though obviously different in scope/plausibility.
Agreed. I also took some time to go through all the books and did it in the end partly out of a sense of duty.
> hah, just noticed your username
:D Initially it was meant to be a throwaway account, but I didn't want to go with the usual throwaway1234 pattern that is common on hn.
> the politics and philosophy of dune are even more interesting than mars, though obviously different in scope/plausibility.
Also agreed. It's not easy for me to say which of the two conveys more insight into the human condition and human societies. Dune is certainly grander and bolder in vision, with lots of surprising speculation. Otoh, Mars credibly captures the anarchic dynamics that would arise were we to ever actually colonize the planet.
In the end they both have something to offer, though for me Dune remains the greater series.
I didn't continue. If that isn't the case I will gladly try again.
What would be the best way to experiment with it, other than contacting Levidian Nanosystems and/or Dr. Tour and ask them?
This is basically science, backed by some know-how of what possibly may happen.
Asbestos is just a silicate, which is also not harmful in many cases, including almost anything made of glass. The problem is the physical form, not the chemical composition or the atomic-scale structure.
Not to say that graphene is carcinogenic; I don’t know the literature. But it probably should not be dismissed out of hand purely because graphite is common.
> That's where Andre Geim and Konstantin Novoselov came in. They took a hunk of graphite and used Scotch tape to peel off layer after layer after layer. Geim and Novoselov then analyzed what they had left, and found graphene. For their discovery – which was published in 2004 – they were awarded the 2010 Nobel Prize in Physics.
https://science.osti.gov/Science-Features/News-Archive/Featu...
That's just for things that you are supposed to do, only too much of. Graphene is not useful or an important part of your body's functions; doing things you aren't even supposed to be doing with it (breathing it in, for example) can only have a negative effect.
Speaking of pure carbon, carbon nanotubes are known to cause lung tumors.
Small particles of ANYTHING entering the lungs isn't exactly healthy.
microplastics polluting every organ of every organism on the planet would like a word with you
Well but not just, it's the carbon cycle. So any sink for carbon is decarbonising.
I guess all these example could be the basis for nerdy in-jokes. For example, because of poor naming conventions we are in the situation where the solution to THE Corona virus could be A Corona virus. Just speculating (actually less lethal strains are perhaps the solution).
Will this add a graphene-flake problem to a microplastics problem?
Spaywall for the win.
> a feature, function, or application of a new technology or product which is presented as virtually indispensable or much superior to rival products