Though I'm not sure if the documentation and community support is as good now as it was back in 2001-2003.
I tried Gentoo and it took a long time to install (stage 1, for Gentoo geeks) but by following their documentation and wiki articles I finally had a working Linux system. Which I promptly broke by doing something like `chmod -R 644 /usr` and had to subsequently re-install. Doh! Anyway the point is just that Gentoo was the best Linux distro for me at that time because it worked, had good and extensive documentation, and a helpful community. Learning a lot about how a Linux system is put together and how it works was basically just a bonus. In hindsight it was a really important bonus.
I believe you are thinking of this HN story:
http://www.h-online.com/open/features/Arch-Linux-It-is-what-...
the real difference is that the predominant number of packages in gentoo are compiled specifically for one's machine based off of the specific set of use flags and package.use, and package.mask parameters, and relatively few precompiled binaries exist for gentoo. with arch, there are a lot more precompiled binaries and not having to compile everything from scratch (yes, i know you still can with arch, but this is not the default model) is more appealing to some.
all this said, i absolutely love emerge. arch's pacman is a very good package manager, but emerge is just amazing in my opinion. for someone just starting with a rolling release distro of linux, i'd say take a look at the documentation for both gentoo and arch and see which one you relate to more. after all, you'll be reading a LOT of documentation either way.