As long as you haven't made the active window full screen, or the window you want to switch to, then yes, it works. But it is painful :P
What's being described as "full screen" windows on macOS is not exactly that, and it's very different than full screen windows on Windows or the standard Linux window managers.
On macOS, when we click on the little green button on top of a window, that window becomes full screen *and* becomes a new single-window workspace.
https://support.apple.com/guide/mac-help/use-apps-in-full-sc...
Except for that annoying quirk, I actually find the interface better (though it definitely took time to get used to it).
It's not the same as fullscreen, because it still has the top mac bar, but that's fine, and it gives me the ability to cmd+tab / cmd+tilde through my windows.