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> In this situation, whichever account logged in first is the account that "owns" the session and has policies applied.

So if you log in to your personal account first, and then into the corporate account, the corporate policies are not applied to either account? There are probably a bunch of corporate types who will be very surprised to learn this…

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I admit I've never tried this so I don't know which policies do or do not apply and how. For things like the play store (which is what I've worked on in the past), only the "primary" account (the one you logged into first) will have access to it so if your secondary account has the play store blocked anyway, you won't be able to use it with that account so it doesn't matter much.

I don't know about other policies.

Typically, the corporate login will be blocked if you attempt this.

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