Having used both in a professional setting - and coming in with a fair bit of programming experience - Matlab is generally a pleasure to use. It's different where it needs to be in order to treat matrices as first class citizens, but otherwise you can apply many of the same intuitions and paradigms that you would in any other language.
R on the other hand... R is a fucking disaster of inconsistency. I find myself incredibly frustrated attempting to do simple and sane things - things that I know are only a line or two in Matlab (or even python) and instead fighting with "which version of the 12 different slight variations of this operator are you attempting to use today!" hell scape.
My strong guess is that if you have no coding experience, and you learn R fairly thoroughly - it will feel very nice. My problem is that for anyone with actual coding experience, it's like being given a keyboard with a qwerty layout, but which is actually using dvorak. All your intuitions are pointlessly wrong - not because they are actually problematic, but because R has decided that the A key is really on the other side of the fucking keyboard.
They each have a few strengths over the other, but generally speaking, I much prefer the language consistency of Matlab.
My general experience is - industrial shops will be using Matlab. Almost all of my Matlab work was aerospace related (think sigint/radar/signal processing/modeling).
R is more popular in education environments - but I strongly suspect that's just because it's free. Post-grads don't have much lab funding to work with at the best of times, and Matlab with an associated set of plugins/libraries specific for your task can easily run 30k a seat.
Personally - I find it pretty telling that most places with money choose Matlab. Doesn't inherently make it better, but it does mean Matlab is getting used in places where mistakes are expensive, and there's a focus and consistency to the tooling that I just think is desperately lacking in R.
I rarely found an important difference between the languages besides having to transpose some matrices here and there.