Rossum's Universal Robots
en.wikipedia.org
en.wikipedia.org
Also, while it's really talking about stuff going on at its own time, War with the Newts is pretty good: https://en.wikipedia.org/wiki/War_with_the_Newts
in which it turns out that you really can achieve 100% mass/energy controlled conversion, but, what is left over is the little spark of the Divine in all things…
Perhaps Asimov's 3 Laws of Robotics might need a fourth one adding - #) Any AI must honestly identify themselves as such if asked.
Although quite where that should slot in (eg Above rule 1 or as the final one?) makes for an interesting thought experiment on edge cases.
What if identifying as an AI would harm that human? If so then it should be at the end of the rules.
However, given the "This is why we can't have nice things" factor of human nature or the “What if a sufficiently developed AI decided that self-protection by denial was the best thing to do in a certain situation?” type of scenarios then perhaps as rule #1?
I read somewhere once that Isaac Asimov was a pioneer in writing stories about benevolent robots. His robots were neurologically incapable of harming humans (except for a few who could convince themselves to do so to help humanity as a whole).
The whole Fred Saberhagen "Berserker" series can be thought of as the other side of that action, with Asimov's robots in the role of the berserkers.
No actual robot will ever be constrained by any such "law".
Which storyline is that? I remember the opposite, when R. Giskard intentionally renders the Earth uninhabitable to push humanity out to the stars.