I'm not sure but to speculate:
1. I drove fast on the Autobahn. I'm usually cruising at 160kph+, and did the same with the Tesla. Doing some homework, this kills efficiency fast. I imagine your brother was driving slower. Probably more within the high efficiency band.
2. Temperature delta. It was -5C + wind chill for most of our trip, and much colder up the mountain.
3. I kept a healthy battery reserve when seeking chargers (10%+) Tesla owners seem to encourage letting the battery drop below even 5% as this means an even faster charge to 60%. I am told there is an optimal cadence to charging which I suppose one perfects over time.
4. I did not conserve heating, as I'm told many EV owners do on longer trips. My wife likes our car to be subtropical.
5. Our Tesla might have been abused, though I recall it having <20,000km.
6. 1,000km is 17% shorter than my trip, further compounding (reducing) these differences.
7. Maybe my regenerative braking was set to low. I didn't think or know to check.
8. My route took me to at least a few regular chargers instead of superchargers. Maybe if I had been smarter and spent more time planning I could have used only super chargers.
9. Perhaps you stopped for a lot of breaks, reducing the relative advantage you might have had in your car.
10. Perhaps he left more than an hour earlier than you.
11. Perhaps my charging lines were longer than his.
I'm sure there are many other factors I'm not considering.