The DNA would be sequenced, compared to Earth's life forms, and if no relation is found then it should be explained. For me it would exponentially increase the probabilities of more life in the Universe.
EDIT: Found this https://en.wikipedia.org/wiki/Hypothetical_types_of_biochemi...
* DNA/RNA are not the only options. Other nucleobases potentially exist and artificial ones have certainly been created (1)
* A completely unique sequence would indicate no shared ancestor even if it was DNA.
* We're not sure how life started on Earth either. It could've been more than once in more than one way. We don't know.
* Earth and Mars shared material as asteroid impacts ejected material that eventually landed on the other. Some microorganisms could potentially survive the journey.