Discussing only on the merits of their content, and stipulating that this is neither here nor there with respect to Netflix's long-term prospects vs. HBO:
Breaking Bad isn't an HBO show. So I assume we're just asking, "has Netflix produced any world-class content". The answer to that is yes.
The jewel in their crown, their "Game of Thrones", is clearly Stranger Things. It's undeniably successful, each new season a cultural event. I'd put Stranger Things up against any HBO show for relevance and impact. (Perhaps not for artistic excellence; but, The Wire is the best show that's ever been on television, and it's far from the most watched).
Add to that Black Mirror, Bojack Horseman, Sex Ed, the annual Flanagan miniseries (Hill House, Bly Manor, Midnight Mass), Master of None, and Big Mouth.
They're doing about as well as any premium cable channel ever has. Doesn't, of course, mean you like their content! But I have about as much faith in Netflix coming up with a new prestige show than I do in HBO, most of whose recent stuff has left me pretty cold.