Also if you were to build just 2 or 3 of them, you can't expect any economy of scale.
On top of that, the operational cost of JWST is expected to be around 1B$ for it's lifetime, you could expect that to be similar for every single replica you have.
And finally, you can only put one per rocket, and just the rocket is about 200M$ dollar, and you need to add all the cost of shipping the telescope to Guyana, that's not cheap.
So overall, while a second replica would not cost you another 10B, it would probably cost in the order of 3-5B$, that's a lot of billions for a telescope with exactly identical capabilities to another one. It would still be useful, as astronomers are going to have to compete for time on the JWST and not everyone will be served, but the benefits of a second one would be marginal compared to the benefits of the first one. So the price/benefit ratio might actually be worse on a new copy.
Meanwhile, there is a myriad of other very cool NASA projects that would greatly benefit from 3-5B$ instead and do things that we haven't done so far.