After all, when you brake hard with a car or motorbike or bicycle, it's the front wheel, well in front of the centre of mass, that does almost all the work.
In a single wheel vehicle, the wheel well in front of the centre of mass.... isn't there. In a unicycle that means you're flying off the front (it's even worse in a monowheel) so you'd better not be going faster than a man can run.