Using LD_PRELOAD you cannot hook a syscall like open().
So an app calls the open() function. This results in an unresolved symbol which the run-time linker matches up with the open() exported by glibc. glibc then does the open() syscall.
If libc implements it, then it is by definition in section 3.
EDIT: (signing out of this sub-thread)
Have you ever called a system call by hand using assembly?
Have you ever looked at glibc's source?
Habe you ever looked at the kernel's close() syscall?
You might even have several libc's in your system. You might have a uClibc + Busybox based initrd and a full glibc based root system.
Btw. how does LD_PRELOAD act together static binaries?