Estimates are that there are 10^78 -- 10^82 atoms in the observable universe.
10^100 would be a number greater than either of these values. That's the named large number googol.
A googolplex is 10^10^100 ... that is, ten raised to the power of ten raised to the power of a googol.
There are notations for describing yet larger numbers.
One of these is Knuth's up-arrow notation, in which an upward-pointing arrow (↑) indicates iterated exponentiation.[1]
2↑4 = 2 * (2 * (2 * 2)) = 2^4 = 2^16
2↑↑4 = 2↑(2↑(2↑2) = 2^16 = 65,536
2↑↑↑4 is harder to describe, especially with the typographic limitations of HN.
It is 2↑↑(2↑↑(2↑↑2)), which is 2^2, itself raised to the power of 2, and so forth, 2^65,536 times. (The Wikipedia article represents this more clearly, though omitting ... some detail...)
The number is immensely large. It is immensely larger than the number of atoms, or subatomic particles (roughly 1 electron and 3 quarks per atom), or Planck lengths (~10^53), or Planck volumes (~10^53^3), in the observable universe. And yet it can be represented.
And it's hardly the largest representable number.[2]
The up-arrow notation itself can be more concisely represented as ↑^n, where n is the number of arrows: ↑^2 = ↑↑, ↑^3 = ↑↑↑, etc.
And all of these are simply representations of integer numbers. There are infinitely many integers, and given a need, a sufficiently concise set of expressions can be constructed to describe these.
Infinity is like, really big, man.[3]
There is no bound on points. There is no bound on monetary units which can be created. There is a bound on what those can represent, but that is a separate argument. Money != value. Money is a unit of measurement of value.
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Notes:
1. See generally: https://en.wikipedia.org/wiki/Knuth%27s_up-arrow_notation
2. See generally: https://en.wikipedia.org/wiki/Large_numbers
3. I won't even get to different sizes of infinities, though that's a fun exercise. See for example Cantor's Diagonal Argument: https://en.wikipedia.org/wiki/Cantor%27s_diagonal_argument