What happens when the Sinology dies? Do I have to buy another Synology to mount my array again? Does it have to be the same model, or family of models?
https://kb.synology.com/DSM/tutorial/How_can_I_recover_data_...
The vendor NASes do seem to add extra partitions besides just one main 'md0', though—so you probably couldn't expect to yank the drives from a Synology and pop them into an ASUSTOR directly.
I also tested pulling drives configured in the Drivestor and putting them in the Lockerstor, and that worked, but there were quirks if I tried in the opposite direction.
In the end, I would rather make sure I have a complete/separate backup of the NAS before attempting to move the drives, just in case.