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You mean Rf7 when he ignored the *pawn on e6 being attacked by the queen for a potential fork with the knight (Qxe6 Ng7+)?

I'm referring to move 133, right after Ian moved his queen from H6 to H7, attacking the rook. Magnus ignores this and moves his E5 pawn to E6. https://www.youtube.com/watch?v=PWkBeTwbfj4&t=29890s