This is of course all separate from whether you can actually physically go offline from work, too. If a Slack ping at any time causes you to reopen your work laptop, even if you have different surroundings, you can't really fully escape "work mode." If you always wake up immediately into dealing with work, your bed becomes a "work area" too...
I have found myself missing the work commute more and more. Granted, I had a pretty nice one (15min train, 10min walk; not spending hours in traffic), but the biggest benefit I'm retroactively realizing was the clear separation between work and home. Working on finishing up a commit? Too bad, gotta run to catch a train, and then I'm no longer in work mode. Thinking about that bug the next morning? Maybe, but can still allow some personal time in the morning because not really "at work" until the physical commute in.