Think of all the fusion powered direct air CO2 capture we could have <3
The first landmark is to make coal plants unprofitable. Once all (most of) the coal and oil plants are closed, it would be interesting to use the spare electricity for carbon capture. Otherwise you are burning coal to power the carbon capture facility.
Oh, trees? ;-)
The fusion energy that is powering the system is that of our sun. No perpetual motion machine required, our planet is being bathed in outside energy.
Trees are still great though, for innumerable other reasons.
Of course, by the time we have spare fusion power, that'll also have replaced much of those 40 gigatons, and Orca is certainly not the upper limit in terms of scale.