Do you want to start at the heavy end or the light end? Solaris is heavy. The Cyberiad (http://en.wikipedia.org/wiki/The_Cyberiad ) is light.
I've never been able to get into his novels, though. Mind you I'm not really a fan of science fiction per se.
Asimov is similarly bad at actual writing, but his ideas are sufficiently good and they come sufficiently thick and fast even in his novels that he's still pretty okay to read.
In contrast an author like Neal Stephenson manages to write a science fiction story with proper characters who are interesting to read about even when they're not expounding on some science-fictional idea.
I admit that I don't know enough (I fail at reading Dostoyevsky) but it is counted as great writing despite lacking in the pace that modern readers desire.